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Inspired by Nature, we present a polypeptide-based organic redox-active material constructed from renewable feedstocks, L-glutamic acid (an amino acid) and riboflavin (vitamin B₂), to address challenges with start-to-end-of-life management in energy storage systems (ESSs). The amino acid was utilized to establish a degradable polymer backbone, along which many copies of riboflavin were incorporated to serve as the redox-active pendant groups that enabled energy storage. The overall synthesis involved the ring-opening polymerization (ROP) of anl-glutamic acid-derivedN-carboxyanhydride (NCA) monomer, followed by side chain activation with azides and, finally, click coupling to achieve installation of alkyne-functionalized riboflavin moieties. The steric bulkiness and rich chemical functionality of riboflavin resulted in synthetic complexities that required reaction optimization to achieve the desired polymer structure. Electrochemical characterization of the resultant riboflavin polypeptide, in organic electrolyte, showed quasireversible redox activity with a half-wave potential (E_1/2) ofca.−1.10 Vvs.ferrocene/ferrocenium (Fc/Fc⁺). Cell viability assays revealed biocompatibility, as indicated by negligible cytotoxicity for fibroblast cells. The polypeptide design, consisting of labile amide backbone linkages and side-chain ester functionalities that tethered the riboflavin units to the backbone, enabled hydrolytic degradation to recover building blocks for future upcycling or recycling. This bioinspired strategy advances the development of degradable redox-active polymers and promotes sustainable materials design for circular energy storage technologies. 

Non-aqueous organic redox flow batteries (NAORFBs) are considered emerging large-scale energy storage systems due to their larger voltage window as compared to aqueous systems and their metal-free nature. However, low solubility, sustainability, and crossover of redox materials remain major challenges for the development of NAORFBs. Here, we report the use of redox active α-helical polypeptides suitable for NAORFBs. The polypeptides exhibit less crossover than small molecule analogs for both Daramic 175 separator and FAPQ 375 PP membrane, with FAPQ 375 PP preventing crossover most effectivley. Polypeptide NAORFBs assembled with a TEMPO-based polypeptide catholyte and viologen-based polypeptide anolyte exhibit low capacity fade ( ca. 0.1% per cycle over 500 cycles) and high coulombic efficiency (>99.5%). The polypeptide NAORFBs exhibit an output voltage of 1.1 V with a maximum capacity of 0.53 A h L −1 (39% of the theoretical capacity). After 500 charge–discharge cycles, 60% of the initial capacity was retained. Post cycling analysis using spectral and electrochemical methods demonstrate that the polypeptide backbone and the ester side chain linkages are stable during electrochemical cycling. Taken together, these polypeptides offer naturally-derived, deconstructable platforms for addressing the needs of metal-free energy storage. 

The role of the linker (the group connecting viologen moieties to peptide-based backbones) in electron transfer was studied. The backbone dictated the mechanism of electron transfer, whereas the linker length altered the rate of electron transfer. 

Abstract Radiogenic neutrons emitted by detector materials are one of the most challenging backgrounds for the direct search of dark matter in the form of weakly interacting massive particles (WIMPs). To mitigate this background, the XENONnT experiment is equipped with a novel gadolinium-doped water Cherenkov detector, which encloses the xenon dual-phase time projection chamber (TPC). The neutron veto (NV) can tag neutrons via their capture on gadolinium or hydrogen, which release$$\gamma $$ $\gamma$-rays that are subsequently detected as Cherenkov light. In this work, we present the first results of the XENONnT NV when operated with demineralized water only, before the insertion of gadolinium. Its efficiency for detecting neutrons is$$({82\pm 1}){\%}$$ $\left(82\pm 1\right)\%$, the highest neutron detection efficiency achieved in a water Cherenkov detector. This enables a high efficiency of$$({53\pm 3}){\%}$$ $\left(53\pm 3\right)\%$for the tagging of WIMP-like neutron signals, inside a tagging time window of$${250}~{\upmu }\hbox {s}$$ $250\mu \text{s}$between TPC and NV, leading to a livetime loss of$${1.6}{\%}$$ $1.6\%$during the first science run of XENONnT. 

We report on a blinded search for dark matter with single- and few-electron signals in the first science run of XENONnT relying on a novel detector response framework that is physics model dependent. We derive 90% confidence upper limits for dark matter-electron interactions. Heavy and light mediator cases are considered for the standard halo model and dark matter up-scattered in the Sun. We set stringent new limits on dark matter-electron scattering via a heavy mediator with a mass within $10–20\mathrm{MeV}/c^2$and electron absorption of axionlike particles and dark photons for $m_{\chi }$below $0.03\mathrm{keV}/c^2$. Published by the American Physical Society2025 

The XENONnT experiment, located at the INFN Laboratori Nazionali del Gran Sasso, Italy, features a 5.9 tonne liquid xenon time projection chamber surrounded by an instrumented neutron veto, all of which is housed within a muon veto water tank. Because of extensive shielding and advanced purification to mitigate natural radioactivity, an exceptionally low background level of $(15.8\pm 1.3)\mathrm{events}/(\mathrm{tonne}·\mathrm{year}·\mathrm{keV})$in the (1,30) keV region is reached in the inner part of the time projection chamber. XENONnT is, thus, sensitive to a wide range of rare phenomena related to dark matter and neutrino interactions, both within and beyond the Standard Model of particle physics, with a focus on the direct detection of dark matter in the form of weakly interacting massive particles. From May 2021 to December 2021, XENONnT accumulated data in rare-event search mode with a total exposure of one $\mathrm{tonne}·\mathrm{year}$. This paper provides a detailed description of the signal reconstruction methods, event selection procedure, and detector response calibration, as well as an overview of the detector performance in this time frame. This work establishes the foundational framework for the “blind analysis” methodology we are using when reporting XENONnT physics results. Published by the American Physical Society2025 

We search for dark matter (DM) with a mass $[3,12]\mathrm{GeV}/c^2$using an exposure of $3.51\mathrm{tonne}\hspace{0.17em}\mathrm{year}$with the XENONnT experiment. We consider spin-independent DM-nucleon interactions mediated by a heavy or light mediator, spin-dependent DM-neutron interactions, momentum-dependent DM scattering, and mirror DM. Using a lowered energy threshold compared to the previous weakly interacting massive particle search, a blind analysis of [0.5, 5.0] keV nuclear recoil events reveals no significant signal excess over the background. XENONnT excludes spin-independent DM-nucleon cross sections $>2.5\times {10}^{-45}{\mathrm{cm}}^2$at 90% confidence level for $6\mathrm{GeV}/c^2$DM. In the considered mass range, the DM sensitivity approaches the “neutrino fog,” the limitation where neutrinos produce a signal that is indistinguishable from that of light DM-xenon nucleus scattering. Published by the American Physical Society2025